We present explicit evaluation of K-shell ionization caused by photoel
ectric absorption, by Compton scattering, and by electron collisions i
n supernovae envelopes. Each process derives from the radioactivity th
at dominates the bolometric luminosity of the model supernovae. We inc
lude the ionization by bremsstrahlung. We find that electron-collision
ionization with decelerating Compton electrons is the dominant proces
s of K-shell ionization for light elements (lighter than Si) whereas p
hotoelectric K-shell absorption of Comptonized gammas is the dominant
process of K-shell ionization for heavy elements (like Fe). The relati
ve importance of the ionization processes also depends upon compositio
n and upon time, as well as upon supernova type. For Type Ia all four
ionization sources are of importance. We present fitting formulas for
the deposition of radioactive power in each class of models studied. T
he energy deposition of all mechanisms decreases with time, including
the rate of K-shell ionizations of all elements throughout the superno
vae model evaluated herein. We compare the relative contributions to t
he energy deposition and confirm with greater numerical detail results
already established.