Vv. Flambaum et al., STRUCTURE OF COMPOUND STATES IN THE CHAOTIC SPECTRUM OF THE CE ATOM -LOCALIZATION PROPERTIES, MATRIX-ELEMENTS, AND ENHANCEMENT OF WEAK PERTURBATIONS, Physical review. A, 50(1), 1994, pp. 267-296
The aim of the present paper is to analyze a realistic model of a quan
tum chaotic system: the spectrum and the eigenstates of the rare-earth
atom of Ce. Using the relativistic configuration-interaction method t
he spectra and the wave functions of odd and even levels of Ce with J
= 4 are calculated. It is shown that the structure of the excited stat
es at excitation energies above 1 eV becomes similar to that of the co
mpound states in heavy nuclei. The wave functions of the excited state
s are chaotic superpositions of the simple basis states (with the numb
er of ''principal'' components N approximately 100), built of the 4f,
6s, 5d, and 6p single-electron orbitals. The localization of the eigen
states on the energy scale is characterized by the spread width GAMMA
approximately ND, where D is the average level spacing (D approximatel
y 0.03 eV). The emergence of chaos in the spectrum and the dependence
of the N and GAMMA parameters on the excitation energy are studied. Th
e shape of the localization is shown to be Lorenzian around the maximu
m (principal components), whereas outside this region the squared comp
onents display a faster decrease, in agreement with the perturbation t
heory treatment of the band random matrix (BRM) model. The structure o
f the real interaction matrix is compared with that assumed in the BRM
models. A formula expressing the mean-squared values of matrix elemen
ts between the eigenstates in terms of their parameters and single-par
ticle occupancies is derived, and its applicability is checked with th
e results of numerical calculations. The hypothesis of a Gaussian dist
ribution of the eigenstates' components and matrix elements between th
e eigenstates has been checked. The existence of the statistical (dyna
mical) enhancement of weak perturbations in systems with dense spectra
is demonstrated.