Mj. Nadeau et al., ELECTRIC DISSOCIATION OF NEGATIVE-IONS .2., Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 92(1-4), 1994, pp. 265-269
As an alternative to naturally occurring negative ion discrimination,
we have used electric dissociation to discriminate between isobars, by
destroying the weaker negative ion of a pair. This technique also per
mits the determination of the properties of the quantum states and the
binding energy of some weakly bound negative ions (Ca, Tm, Dy and Yb)
, some of which had not been studied previously (Tm, Dy, Yb). During t
he course of this study, it was also established that some very weakly
bound negative ions (Dy and Yb) are destroyed by weak electric fields
such as those in tandem accelerators. This fact was used to verify th
e theory of electric dissociation by the comparison of the dissociatio
n probability under different field configurations and gradients. The
results regarding the lanthanide elements indicate that in all three c
ases the extra electron occupies a p orbital which does not follow the
''natural'' filling of the periodic table. The study of Ca- concluded
that the lowest states are the 4s(2)4p P2 J = 1/2, 3/2 states with bi
nding energy of 21.0 +/- 2.5 meV and a spin-orbit splitting in the ran
ge 0.4-.5 meV with a maximum probability at 0.75 meV. The ordering of
the levels has not yet been established.