Dh. Lowndes et al., SMOOTH POLYCRYSTALLINE CERAMIC SUBSTRATES WITH ENHANCED METAL ADHESION BY PULSED EXCIMER-LASER PROCESSING, Applied physics letters, 64(14), 1994, pp. 1791-1793
Multishot pulsed XeCl (308 nm) excimer laser irradiation of commercial
fine-grained polycrystalline alumina substrates is found to significa
ntly improve their properties for metal film-bonding-applications. A s
moother surface finish is obtained, and the adhesion strength of subse
quently deposited copper films to the laser-treated alumina surface is
increased by a factor of 3-5 (200%-400%) under optimum laser conditio
ns. Smoothing occurs when the alumina melts and undergoes molten flow
before resolidifying. XPS measurements suggest that electrical activat
ion of the near-surface region also may contribute to the enhanced cop
per adhesion.