Dj. Rogers et al., INVESTIGTIONS OF COMPOSITIONAL SEPARATION OF CO-CR-TA CR THIN-FILM RECORDING MEDIA, Journal of magnetism and magnetic materials, 135(1), 1994, pp. 82-88
The compositional distribution in Co-Cr-Ta thin films is investigated
as a function of Cr underlayer texture and substrate temperature (T(s)
) using spin-echo nuclear magnetic resonance and preferential chemical
etching. Both the extent and pattern of compositional separation (CS)
show no variation with Cr underlayer texture. Elevated T(s) is observ
ed to promote both CS and grain boundary Cr enrichment. The magnetic a
nisotropy fields of Co-enriched components in the films are observed t
o increase with T(s), explaining the T(s), dependence of H(c). Ta addi
tion is observed to control the distribution of Co and Cr, leading to
a unique compositional microstructure which may enhance the magnetic a
nd recording properties.