Glass ceramics, prepared by the controlled devitrification of glasses,
have become established in a wide range of technical and technologica
l applications, ranging from domestic usage through to heavy electrica
l engineering and microelectronics. The genesis of glass ceramic mater
ials in the 1950s is reviewed together with the various studies in nuc
leation and crystallisation phenomena that have subsequently taken pla
ce. The property requirements for specific applications are given and
the selection and development of glass ceramics that will fit these ne
eds are discussed. Comparisons with other glass and ceramic materials
are drawn which illustrate the preferential selection of glass ceramic
s for various uses.