COMPLEX RESONANCES IN THE PREDISSOCIATION OF CS2

Authors
KIM B YOSHIHARA K LEE S
Citation
B. Kim et al., COMPLEX RESONANCES IN THE PREDISSOCIATION OF CS2, Physical review letters, 73(3), 1994, pp. 424-427
Citations number
27
Categorie Soggetti
Physics
Journal title
Physical review letters → ACNP
ISSN journal
00319007
Volume
73
Issue
3
Year of publication
1994
Pages
424 - 427
Database
ISI
SICI code
0031-9007(1994)73:3<424:CRITPO>2.0.ZU;2-A
Abstract
We present detailed quantum mechanical analysis of the complex resonan ces observed in molecular predissociation. The complex features in the photodissociation spectrum of Cs2 are reproduced well by the close-co upling calculation including three channels. A very narrow resonance w ith a linewidth of approximately 2 x 10(-7) cm-1 is predicted. It is s hown that q reversal can occur in predissociation with only two channe ls involved.