ROTATIONALLY RESOLVED SPECTROSCOPY ON THE 1-CYANONAPHTHALENE TRIETHYLAMINE VAN-DER-WAALS COMPLEX IN A MOLECULAR-BEAM

Authors
BERDEN G MEERTS WL
Citation
G. Berden et Wl. Meerts, ROTATIONALLY RESOLVED SPECTROSCOPY ON THE 1-CYANONAPHTHALENE TRIETHYLAMINE VAN-DER-WAALS COMPLEX IN A MOLECULAR-BEAM, Chemical physics letters, 224(3-4), 1994, pp. 405-410
Citations number
12
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
224
Issue
3-4
Year of publication
1994
Pages
405 - 410
Database
ISI
SICI code
0009-2614(1994)224:3-4<405:RRSOT1>2.0.ZU;2-D
Abstract
The rotationally resolved fluorescence excitation spectrum of the 0(0) 0 band in the S1 <-- S0 transition, at almost-equal-to 318 nm, of the 1-cyanonaphthalene/triethylamine van der Waals complex has been record ed using laser-induced fluorescence in a molecular beam apparatus. Thi s spectrum could be fitted to a pure a-type band. From the rotational constants a T-shaped geometry could be deduced.