VALENCE STATES OF SM IN SMRUSN3

Citation
Ad. Chinchure et al., VALENCE STATES OF SM IN SMRUSN3, Physical review. B, Condensed matter, 50(1), 1994, pp. 609-611
Citations number
9
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
01631829
Volume
50
Issue
1
Year of publication
1994
Pages
609 - 611
Database
ISI
SICI code
0163-1829(1994)50:1<609:VSOSIS>2.0.ZU;2-N
Abstract
To obtain a better insight into the nature of valence states of Sm ion s in SmRuSn3 and to verify the differing conclusions reached by T. Fuk uhara, I. Sakamoto, and H. Sato [J. Phys. Condens. Matter 3, 8917 (199 1)] and C. Godart et al. [Phys. Rev. B 48, 16 402 (1993)], we have sys tematically analyzed the magnetic-susceptibility data by considering t he effects of crystalline electric field, exchange interaction, and va lence fluctuation. In this compound, Sm ions occupy two different site s, 6d and 2a, in the ratio of 3:1. Our analysis shows that Sm ions at the 6d site are in a trivalent state and those at the 2a sites are in a valence fluctuating state. This supports the claim made by C. Godart et al. [Phys. Rev. B 48, 16 402 (1993)].