A BIOMIMETIC SYNTHESIS OF A NOVEL SECO INDOLE ALKALOID, 11-METHOXYGELSEMAMIDE

Authors
TAKAYAMA H KITAJIMA M SAKAI S
Citation
H. Takayama et al., A BIOMIMETIC SYNTHESIS OF A NOVEL SECO INDOLE ALKALOID, 11-METHOXYGELSEMAMIDE, Tetrahedron, 50(28), 1994, pp. 8363-8370
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
28
Year of publication
1994
Pages
8363 - 8370
Database
ISI
SICI code
0040-4020(1994)50:28<8363:ABSOAN>2.0.ZU;2-E
Abstract
A new type of Gelsemium alkaloid, 11-methoxygelsemamide (2), having a 1,2-secoindole system, was synthesized for the first time from a sarpa gine type indole alkaloid, gardnerine (6), based on a suggested biogen etic sequence.