A NOVEL GENERAL-METHOD FOR 2-AMINOGLYCAL SYNTHESIS

Citation
F. Iglesiasguerra et al., A NOVEL GENERAL-METHOD FOR 2-AMINOGLYCAL SYNTHESIS, Tetrahedron letters, 35(28), 1994, pp. 5031-5034
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
28
Year of publication
1994
Pages
5031 - 5034
Database
ISI
SICI code
0040-4039(1994)35:28<5031:ANGF2S>2.0.ZU;2-M
Abstract
The first general method for N,N-substituted 2-aminoglycals is reporte d. We describe the syntheses of 2-[(N-acyl-N-alkyl)amino] and ,6-O-ben zylidene-2-deoxy-erythro-hex-1-en-3-uloses by oxidation of glycoside d erivatives of N,N-substituted-2-aminosugars using two oxidant systems. Reactions proceed with good yields.