NOVEL REACTIVITY OF STABILIZED METHYLENETRIBUTYLPHOSPHORANE - A NEW MITSUNOBU REAGENT

Authors
TSUNODA T OZAKI F ITO S
Citation
T. Tsunoda et al., NOVEL REACTIVITY OF STABILIZED METHYLENETRIBUTYLPHOSPHORANE - A NEW MITSUNOBU REAGENT, Tetrahedron letters, 35(28), 1994, pp. 5081-5082
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
28
Year of publication
1994
Pages
5081 - 5082
Database
ISI
SICI code
0040-4039(1994)35:28<5081:NROSM->2.0.ZU;2-2
Abstract
Cyanomethylenetributylphosphorane was shown to mediate the direct cond ensation of alcohols with O- and N-nucleophiles. A secondary alcohol, 2-octanol, reacted satisfactorily with Walden inversion of its carbiny l carbon.