A pretreatment method for dyeing Kevlar(R) fibers without dye carriers
has been developed. Fibers were metalated by reacting with a methylsu
lfinyl anion, the metalated fibers were dyed with cationic and direct
dyes, and the resulting coloration and physical properties were evalua
ted. The results show that this pretreatment technique can improve the
dyeability of Kevlar without compromising mechanical properties. Meta
lation improved dyeability more than grafting with either adipoyl chlo
ride, benzoyl chloride, or vinyl benzyl chloride.