ABSTRACTION OF THE PYS LIGAND FROM [RE2RU2(MU-4-S)(MU-C5H4N)(MU-PYS)(CO)13] BY [RU3(CO)12] - CRYSTAL-STRUCTURE OF [RE2RU2(MU-H)(MU-4-S)(MU-C5H4N)(CO)14]

Authors
COCKERTON BR DEEMING AJ
Citation
Br. Cockerton et Aj. Deeming, ABSTRACTION OF THE PYS LIGAND FROM [RE2RU2(MU-4-S)(MU-C5H4N)(MU-PYS)(CO)13] BY [RU3(CO)12] - CRYSTAL-STRUCTURE OF [RE2RU2(MU-H)(MU-4-S)(MU-C5H4N)(CO)14], Polyhedron, 13(12), 1994, pp. 1945-1949
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
12
Year of publication
1994
Pages
1945 - 1949
Database
ISI
SICI code
0277-5387(1994)13:12<1945:AOTPLF>2.0.ZU;2-7
Abstract
The cluster [Re2Ru2(mu4-S)(mu-C5H4N)(mu-pyS)(CO)13] (pyS = pyridine-2- thionato) reacts with [Ru3(CO)12] at 150-degrees-C to give the product [Re2RU2(mu-H)(mu4-S)(mu-C5H4N)(CO)14], which contains the same arrang ement of metal atoms around the tetrahedral sulphur ligand as the pare nt. The loss of the pyS ligand is compensated for by the addition of a hydride and a carbonyl ligand and by the formation of an Re-Re bond.