NEW ACTINIDE HYDROGEN TRANSITION-METAL COMPOUNDS - SYNTHESIS OF C12H24O6)][(ETA-C(5)ME(5))(2)(CL)UH6RE(PPH(3))(2)] AND THE CRYSTAL-STRUCTURE OF ITS BENZENE SOLVATE

Authors
CENDROWSKIGUILLAUME SM LANCE M NIERLICH M VIGNER J EPHRITIKHINE M
Citation
Sm. Cendrowskiguillaume et al., NEW ACTINIDE HYDROGEN TRANSITION-METAL COMPOUNDS - SYNTHESIS OF C12H24O6)][(ETA-C(5)ME(5))(2)(CL)UH6RE(PPH(3))(2)] AND THE CRYSTAL-STRUCTURE OF ITS BENZENE SOLVATE, Journal of the Chemical Society, Chemical Communications, (14), 1994, pp. 1655-1656
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
14
Year of publication
1994
Pages
1655 - 1656
Database
ISI
SICI code
0022-4936(1994):14<1655:NAHTC->2.0.ZU;2-L
Abstract
The title compound is isolated from the reaction of [{U(C(5)Me(5))(2)( mu-Cl)}(3)] with [K(18-crown-6)][ReH6(PPh(3))(2)] (18-crown-6 = 1,4,7, 10,13,16-hexaoxacyclooctadecane) and is oxidized by TlBPh(4) into the neutral derivative [(C(5)Me(5))(2)(Cl)UH6Re(PPh(3))(2)]; the H-1 NMR s pectra reveal that in both complexes, the uranium and rhenium atoms ar e linked by three bridging hydrides.