THE UNUSUAL STEVENS TYPE REARRANGEMENTS OF SOME DIALKYL SULFIDES ON ARH-RH BOND

Authors
DEVERY MP DICKSON RS
Citation
Mp. Devery et Rs. Dickson, THE UNUSUAL STEVENS TYPE REARRANGEMENTS OF SOME DIALKYL SULFIDES ON ARH-RH BOND, Journal of the Chemical Society, Chemical Communications, (14), 1994, pp. 1721-1722
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
14
Year of publication
1994
Pages
1721 - 1722
Database
ISI
SICI code
0022-4936(1994):14<1721:TUSTRO>2.0.ZU;2-E
Abstract
The coordinative addition of dimethyl sulfide to (C5H5)(2)Rh-2(mu-CO)( mu-CF3C2CF3) is followed by an intramolecular transformation to give ( C5H5)(2)Rh-2(mu-SCH(2)Me){mu-C(CF3)CH(CF3)}, and the corresponding rea ction with Et(2)S gives a related complex with a chiral bridging sulfi de group SCHMeEt.