FERROCENYL-FUNCTIONALIZED POLY(PROPYLENIMINE) DENDRIMERS

Authors
CUADRADO I MORAN M CASADO CM ALONSO B LOBETE F GARCIA B IBISATE M LOSADA J
Citation
I. Cuadrado et al., FERROCENYL-FUNCTIONALIZED POLY(PROPYLENIMINE) DENDRIMERS, Organometallics, 15(25), 1996, pp. 5278-5280
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
25
Year of publication
1996
Pages
5278 - 5280
Database
ISI
SICI code
0276-7333(1996)15:25<5278:FPD>2.0.ZU;2-5
Abstract
New ferrocenyl dendritic macromolecules based on flexible poly(propyle nimine) dendrimer cores, built up to the fifth generation, containing 4, 8, 16, 32, and 64 peripheral ferrocenyl moieties, have been prepare d and characterized. Solution electrochemical studies showed that all the ferrocenyl redox centers attached to the dendritic surface are ele ctrochemically independent and that, in CH2Cl2 and THF as solvents, th e neutral dendrimers undergo oxidative precipitation onto the electrod e surfaces.