INTERACTION OF URANYL MOLYBDATE WITH THE NA2MOO4-NA2MO2O7 MELT

Authors
SMOLENSKII VV BOVE AL MARTEMYANOVA ZS
Citation
Vv. Smolenskii et al., INTERACTION OF URANYL MOLYBDATE WITH THE NA2MOO4-NA2MO2O7 MELT, Russian journal of electrochemistry, 30(6), 1994, pp. 707-710
Citations number
11
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
30
Issue
6
Year of publication
1994
Pages
707 - 710
Database
ISI
SICI code
1023-1935(1994)30:6<707:IOUMWT>2.0.ZU;2-E
Abstract
Behavior of uranyl molybdate in molten Na2MoO4-Na2Mo2O7 salt mixture a t 1073 K in air was studied using cyclic linear volmmetry and potentio metric titration techniques. Uranyl complexes of two types ([UO2(MoO4) 2]2- and UO3MoO42-) were shown to be formed in the solution upon the a ddition of UO2MoO4. The composition of a cathodic product was found to be determined by the molar ratio of these two complexes in the melt.