THE QUANTUM-CHEMICAL MODEL FOR THE 1ST STAGE OF THE COPPER ANODIC IONIZATION IN AQUEOUS-ELECTROLYTE SOLUTIONS

Authors
KUZNETSOV AM MANKO LY SHAPNIK MS
Citation
Am. Kuznetsov et al., THE QUANTUM-CHEMICAL MODEL FOR THE 1ST STAGE OF THE COPPER ANODIC IONIZATION IN AQUEOUS-ELECTROLYTE SOLUTIONS, Russian journal of electrochemistry, 29(10), 1993, pp. 1095-1098
Citations number
19
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
29
Issue
10
Year of publication
1993
Pages
1095 - 1098
Database
ISI
SICI code
1023-1935(1993)29:10<1095:TQMFT1>2.0.ZU;2-I
Abstract
The microscopic-chemical-event mechanism for the first stage of a two- stage anodic copper ionization process was examined by the quantum-che mical FNDO/2 method (i.e., fully disregarding differential overlapping ) and using the electrode-surface cluster model. The calculated exchan ge current density correlates well with that measured experimentally.