We report a theoretical and experimental study of quasiparticle multip
lication in superconductors. A model of the multiplication process, ba
sed on random quasiparticle-phonon inelastic scattering, has been comp
ared with experimental data obtained from double tunnel junction devic
es in which the quasiparticle injection energy can be varied by alteri
ng the bias voltage. Excellent quantitative agreement has been obtaine
d for a variety of device structures provided that a previously uniden
tified quasiparticle energy enhancement process is included in the mod
el. The existence of this energy enhancement process has implications
for quasiparticle trapping and multiplication in practical energy reso
lving detector devices.