THE EFFECT OF ISOVALENT SUBSTITUTIONS IN THE GERMANIUM SUBLATTICE ON THE ELECTRIC PROPERTIES OF LI6.25GE1.75M0.25O7 (M=AL, GA)

Authors
SHEKHTMAN GS APARINA ER BURMAKIN EI ESINA NO
Citation
Gs. Shekhtman et al., THE EFFECT OF ISOVALENT SUBSTITUTIONS IN THE GERMANIUM SUBLATTICE ON THE ELECTRIC PROPERTIES OF LI6.25GE1.75M0.25O7 (M=AL, GA), Russian journal of electrochemistry, 29(11), 1993, pp. 1236-1238
Citations number
8
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
29
Issue
11
Year of publication
1993
Pages
1236 - 1238
Database
ISI
SICI code
1023-1935(1993)29:11<1236:TEOISI>2.0.ZU;2-5
Abstract
The paper reports a study of the effect of the partial substitution of silicon or titanium cations for germanium ions on the resistivity and activation energy for conduction of Li6.25Ge1.75Al(Ga)0.25O7 solid el ectrolytes. The results give ample reason to state that, given a const ant crystal structure and a constant charge-carrier concentration, the electric conductivity of the solid solutions in question is determine d by the geometric factor. The covalence of the rigid lattice, which h as a direct bearing on the strength of the bond between the mobile lit hium cations and oxygen anions, plays an insignificant role.