G. Nounesis et al., EXPERIMENTAL-OBSERVATION OF A TRANSITION BETWEEN 2 UNIAXIAL NEMATIC LIQUID-CRYSTAL PHASES, Physical review letters, 73(4), 1994, pp. 565-568
The experimental observation of a phase transition between two uniaxia
l nematic liquid-crystalline phases is reported. High-resolution x-ray
scattering and ac calorimetric studies on binary mixtures of octyl- a
nd decyloxyphenyl-nitrobenzoyloxy benzoates show evidence of a first-o
rder transition between two nematic phases with different types of sho
rt-range smectic order. This transition is observed in the vicinity of
the termination of the smectic-A(d)-Smectic-A(l) phase boundary, in a
ccordance with theoretical predictions.