PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .33. INVESTIGATION OF A CLUSTER-TYPE MONOMER [FE3O(OCOCH=CH2)6]OH AND ITS POLYMERIZATION PRODUCT BY IR, XPS, MOSSBAUER, AND MASS-SPECTROSCOPY

Authors
SHULGA YM ROSHCHUPKINA OS DZHARDIMALIEVA GI CHERNUSHEVICH IV DODONOV AF BALDOKHIN YV KOLOTYRKIN PY ROZENBERG AS POMOGAILO AD
Citation
Ym. Shulga et al., PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .33. INVESTIGATION OF A CLUSTER-TYPE MONOMER [FE3O(OCOCH=CH2)6]OH AND ITS POLYMERIZATION PRODUCT BY IR, XPS, MOSSBAUER, AND MASS-SPECTROSCOPY, Russian chemical bulletin, 42(10), 1993, pp. 1661-1665
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
10
Year of publication
1993
Pages
1661 - 1665
Database
ISI
SICI code
1066-5285(1993)42:10<1661:PAROMM>2.0.ZU;2-V
Abstract
A new cluster-type monomer [Fe3O(OCOCH=CH2)6]OH . 3H2O was synthesized by the reaction of acrylic acid with freshly prepared iron hydroxide. The monomer was characterized by various physicochemical methods. It has been shown that the acid residues are bound to the metal atoms thr ough carboxyl groups in a bridge-like or bidentate fashion, and the do uble bond does not participate in the coordination. The mechanism of t hermal fragmentation of the [Fe3O(OCOCH=CH2)6]+ cluster was studied. I t was demonstrated that the radical polymerization of this monomer inv olved bidentate acrylate groups. No reduction of Fe3+ during the polym erization was observed.