SALTPAN IMPACT CRATER, SOUTH-AFRICA - GEOCHEMISTRY OF TARGET ROCKS, BRECCIAS, AND IMPACT GLASSES, AND OSMIUM ISOTOPE SYSTEMATICS

Citation
C. Koeberl et al., SALTPAN IMPACT CRATER, SOUTH-AFRICA - GEOCHEMISTRY OF TARGET ROCKS, BRECCIAS, AND IMPACT GLASSES, AND OSMIUM ISOTOPE SYSTEMATICS, Geochimica et cosmochimica acta, 58(13), 1994, pp. 2893-2910
Citations number
50
Categorie Soggetti
Geosciences, Interdisciplinary
ISSN journal
00167037
Volume
58
Issue
13
Year of publication
1994
Pages
2893 - 2910
Database
ISI
SICI code
0016-7037(1994)58:13<2893:SICS-G>2.0.ZU;2-Q
Abstract
The Pretoria Saltpan crater is a well-preserved 220,000 year-old, 1.13 km-diameter, simple impact crater. The crater was formed in Nebo gran ites of the Bushveld Complex. Some minor intrusions thought to be youn ger than the Nebo granite are present at the crater and have earlier b een believed to support a volcanic origin of the structure, but recent geological studies showed them to be part of the regional geology and of Proterozoic age. We studied the petrology and geochemistry of four teen target granite samples, three suevitic breccias, nine intrusive r ocks, as well as melt agglutinates, handpicked impact glass fragments and sulfide spherules from the Saltpan impact crater. Unconsolidated s uevitic breccias recovered from different depths in the crater were fo und to contain abundant evidence of shock metamorphism. The target roc k granites show only limited compositional variability. The major and trace element composition of the bulk breccia is very similar to that of average basement granite. Impact glass fragments recovered from the unconsolidated suevitic breccia have a CIPW normative composition sim ilar to that of the basement granites. No evidence for admixture from any of the minor intrusions was found. The similarity of trace element abundances and ratios, and REE patterns between impact glasses and gr anites favors derivation of the glasses from the granites. The impact glass fragments show considerable enrichments of Mg, Cr, Fe, Co, Ni, a nd Ir, compared to the basement granites. The abundances of these elem ents in the glasses (after correction for indigenous concentrations) c an be explained by admixture of about less-than-or-equal-to 10% of a c hondritic component. High Ir concentrations (almost-equal-to 100 ppb) have been found in sulfide spherule samples, which may complement the (lower) Ir abundances in the glasses and could indicate some fractiona tion during impact. Re-Os isotopic studies were applied to further inv estigate the presence of a meteoritic component in the suevitic brecci a. The target granite shows very low osmium abundances of about 7 ppt and high Os-187/Os-188 ratios of about 0.72 that would be expected for old continental crust. In contrast, the breccia samples were found to have much higher osmium abundances (almost-equal-to 80 ppt) and lower Os-187/Os-188 ratios of about 0.205. These values can be explained by mixing of target rocks with a chondritic component.