INITIAL-STAGES OF COPPER ELECTROCRYSTALLIZATION ON POLYCRYSTALLINE SILVER

Citation
Av. Smolin et al., INITIAL-STAGES OF COPPER ELECTROCRYSTALLIZATION ON POLYCRYSTALLINE SILVER, Russian journal of electrochemistry, 30(2), 1994, pp. 136-141
Citations number
32
Categorie Soggetti
Electrochemistry
ISSN journal
10231935
Volume
30
Issue
2
Year of publication
1994
Pages
136 - 141
Database
ISI
SICI code
1023-1935(1994)30:2<136:IOCEOP>2.0.ZU;2-4
Abstract
The initial stages of copper electrodeposition on polycrystalline silv er were studied by the methods of potentiostatic transients of current , cyclic voltammetry, and electron microscopy. It was shown that the d iffusion model of hemispherical nuclei growth can be applied to estima te relative changes in the formation rate and the number of copper nuc lei. At potentials more positive than the equilibrium potential, an ef fect of depositing copper adatoms on silver was detected.