NEW CATALYTIC-SYSTEM FOR OXIDATIVE CARBONYLATION OF ANILINE

Authors
MACHO V HARUSTIAK M
Citation
V. Macho et M. Harustiak, NEW CATALYTIC-SYSTEM FOR OXIDATIVE CARBONYLATION OF ANILINE, Journal of molecular catalysis, 91(2), 1994, pp. 120000155-120000159
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis → ACNP
ISSN journal
03045102
Volume
91
Issue
2
Year of publication
1994
Pages
120000155 - 120000159
Database
ISI
SICI code
0304-5102(1994)91:2<120000155:NCFOCO>2.0.ZU;2-M
Abstract
Anilines undergo oxidative carbonylation in the presence of methanol, carbon monoxide, oxygen and base. Elemental sulfur or low molecular su lfur derivatives (CS2, COS) were studied as new and efficient catalyst s at temperatures 393-423 K and pressure 8-13 MPa. Methyl-N-phenyl car bamate as product is formed through N,N'-diphenylurea as an intermedia te. Studies of the methanolysis of this intermediate have shown, that this reaction step is catalysed by bases and does not need CO, oxygen or sulfur catalyst.