THE MECHANISM OF THE GIBBS REACTION .2. THE ORTHO-REVERSIBLE-ARROW-ORTHO 2,4-CYCLOHEXADIENE-1-ONE REARRANGEMENT OF THE REACTION-PRODUCT OF 2,6-DI-TERT-BUTYL-4-CHLOROPHENOL AND 2,6-DICHLOROBENZOQUINONE N-CHLOROIMINE

Authors
PALLAGI I TORO A MULLER J
Citation
I. Pallagi et al., THE MECHANISM OF THE GIBBS REACTION .2. THE ORTHO-REVERSIBLE-ARROW-ORTHO 2,4-CYCLOHEXADIENE-1-ONE REARRANGEMENT OF THE REACTION-PRODUCT OF 2,6-DI-TERT-BUTYL-4-CHLOROPHENOL AND 2,6-DICHLOROBENZOQUINONE N-CHLOROIMINE, Tetrahedron, 50(29), 1994, pp. 8809-8814
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
29
Year of publication
1994
Pages
8809 - 8814
Database
ISI
SICI code
0040-4020(1994)50:29<8809:TMOTGR>2.0.ZU;2-B
Abstract
The saturation transfers which were observed during the H-1 NOE differ ence measurements prove an ortho reversible arrow ortho 2,4-cyclohexad iene-1-one rearrangement of the reaction product of 2,6-di-tert-butyl- 4-chlorophenol and 2,6-dichlorobenzoquinone N-chloroimine. This proces s is an intramolecular rearrangement.