SYNTHESIS OF SULFINES BY OXIDATION OF TRITHIOPERESTERS AND THEIR REARRANGEMENT INTO ACYLTRISULFIDES

Authors
LERIVEREND C METZNER P
Citation
C. Leriverend et P. Metzner, SYNTHESIS OF SULFINES BY OXIDATION OF TRITHIOPERESTERS AND THEIR REARRANGEMENT INTO ACYLTRISULFIDES, Tetrahedron letters, 35(29), 1994, pp. 5229-5230
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
29
Year of publication
1994
Pages
5229 - 5230
Database
ISI
SICI code
0040-4039(1994)35:29<5229:SOSBOO>2.0.ZU;2-I
Abstract
Trithioperesters were synthesised by sulfenylation of halomagnesium al kanedithioates with alkylthiotoluenesulfonates and oxidised by mCPBA. The chemoselective conversion of a thiocarbonyl group into a sulfine m oiety was achieved in three cases to yield the first examples of trith ioperester sulfines. These compounds undergo at room temperature a nov el rearrangement to acyltrisulfides.