INTRAMOLECULAR META PHOTOCYCLOADDITION OF 3-BENZYLAZAPROP-1-ENES

Authors
BLAKEMORE DC GILBERT A
Citation
Dc. Blakemore et A. Gilbert, INTRAMOLECULAR META PHOTOCYCLOADDITION OF 3-BENZYLAZAPROP-1-ENES, Tetrahedron letters, 35(29), 1994, pp. 5267-5270
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
29
Year of publication
1994
Pages
5267 - 5270
Database
ISI
SICI code
0040-4039(1994)35:29<5267:IMPO3>2.0.ZU;2-F
Abstract
Photoinduced intramolecular electron transfer in 3-benzylazaprop-1-ene s is inhibited by N-acetyl or N-carbomethoxy protecting groups; fluore scence is then observed from the arene chromophore and intramolecular meta photocycloaddition occurs to give the linear azatriquinane system with high selectivity.