DIBROMOCAMPHOR BROMINATION PRODUCT OF 1-HYDROXYCAMPHENE SKELETON

Citation
R. Antkowiak et Wz. Antkowiak, DIBROMOCAMPHOR BROMINATION PRODUCT OF 1-HYDROXYCAMPHENE SKELETON, Tetrahedron letters, 35(29), 1994, pp. 5283-5284
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
29
Year of publication
1994
Pages
5283 - 5284
Database
ISI
SICI code
0040-4039(1994)35:29<5283:DBPO1S>2.0.ZU;2-Z
Abstract
The formation of -dibromomethylene-2,2-dimethyl-1-hydroxynorbornane as a minor-product of the 3,3-dibromocamphor bromination was found. The structure of this compound was established on the basis of spectral da ta analysis The occurrence of alcohol in the bromination product mixtu re can be taken as evidence supporting the assumed mechanism of campho r methyl group bromination.