O. Betbedermatibet et M. Combescot, ON THE COULOMB ENERGY OF A FINITE-TEMPERATURE ELECTRON-GAS, Journal of statistical physics, 75(5-6), 1994, pp. 953-969
We rederive the Coulomb expansion of the electron gas average energy a
t finite temperature, starting from scratch, i.e., using only the fram
ework of the grand canonical ensemble and not the finite-T Green's fun
ction formalism. We recover the analytical expressions of the exchange
and correlation energy in both the high- T and the T = 0 limits. We e
xplicitly show the origin of the crossover of the correlation energy l
eading term from e4 In e2 at zero temperature to e3 at finite T We als
o discuss the relative importance of exchange and correlation in both
limits.