Considering the phase equilibrium diagram of the Bi2O3-PbO-SrO-CaO-CuO
system, ceramics of the 2223 phase with the composition Bi1.8Pb0.4Sr2
Ca2CU3O10+d have been transformed by a simple annealing procedure into
multi-phase samples. The transformation results in a four-fold increa
se of the critical current density at 2 T and 30 K (three-fold at 1 T
and 50 K), which is believed to express an enhanced pinning capacity o
f the material. The nature of the pinning centres produced is not yet
clarified.