CIRCUMAMBULATORY REARRANGEMENTS OF DITHIOACYLOXY GROUPS AROUND THE CYCLOPENTADIENE RING

Authors
MIKHAILOV IE DUSHENKO GA KOMPAN OE STRUCHKOV YT ZSCHUNKE A MUGGE C DROZD VN MINKIN VI
Citation
Ie. Mikhailov et al., CIRCUMAMBULATORY REARRANGEMENTS OF DITHIOACYLOXY GROUPS AROUND THE CYCLOPENTADIENE RING, Mendeleev communications, (4), 1994, pp. 120-122
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
4
Year of publication
1994
Pages
120 - 122
Database
ISI
SICI code
0959-9436(1994):4<120:CRODGA>2.0.ZU;2-V
Abstract
Circumambulatory rearrangements of dithioacyloxy groups around the cyc lopentadiene ring have been found to occur by a 3,3-sigmatropic shift (hetero-Cope) mechanism with energy barriers in the range of 24-30 kca l mol-1.