QUANTUM-CHEMISTRY OF CHEMISORPTION OF ETHYLENE AT THE ACTIVE-SITE OF ALUMOPHENYLSILOXANE

Authors
NEMUKHIN AV KOLESNIKOV IM VINOKUROV VA
Citation
Av. Nemukhin et al., QUANTUM-CHEMISTRY OF CHEMISORPTION OF ETHYLENE AT THE ACTIVE-SITE OF ALUMOPHENYLSILOXANE, Mendeleev communications, (4), 1994, pp. 144-146
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
4
Year of publication
1994
Pages
144 - 146
Database
ISI
SICI code
0959-9436(1994):4<144:QOCOEA>2.0.ZU;2-Y
Abstract
Quantum chemical calculations provide support for reaction mechanisms suggesting chemisorption of the ethylene molecule on the AlO4 site of alumophenylsiloxane accompanied by pi-bond rupture and the creation of cation-radicals.