VIBRATIONAL CORRECTIONS FOR SOME ELECTRIC AND MAGNETIC-PROPERTIES OF H-2, N-2, HF, AND CO

The effects of vibration on certain electric and magnetic properties o f H-2, N-2, HE and CO are reported. These properties include electric field gradients, generalized Sternheimer shielding constants, electric -field-gradient polarizabilities, nuclear shielding constants, and shi elding polarizabilities. The calculations were based on both electron correlated and uncorrelated methods. Pure vibrational effects, where a ppropriate, were investigated as well as conventional vibrational aver aging. It is found that in many cases vibration plays a very significa nt role.