EFFICIENT ROUTE TO HIGHLY FUNCTIONALIZED TETRAHYDROFURANS BY STEREOCONTROLLED SILICON-DIRECTED CYCLIZATION

Authors
VANDELFT FL VANDERMAREL GA VANBOOM JH
Citation
Fl. Vandelft et al., EFFICIENT ROUTE TO HIGHLY FUNCTIONALIZED TETRAHYDROFURANS BY STEREOCONTROLLED SILICON-DIRECTED CYCLIZATION, Recueil des travaux chimiques des Pays-Bas, 113(6), 1994, pp. 339-341
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Recueil des travaux chimiques des Pays-Bas → ACNP
ISSN journal
01650513
Volume
113
Issue
6
Year of publication
1994
Pages
339 - 341
Database
ISI
SICI code
0165-0513(1994)113:6<339:ERTHFT>2.0.ZU;2-Y
Abstract
Cyclization of lsilyl-l-deoxy-1-phenyldiisopropylsilyl-L-glucitol in t he presence of BF3.Et2O or catalytic H2SO4 proceeds stereoselectively to give predominantly the fully benzylated 2,5-anhydro-L-glucitol deri vative without occurrence of the Peterson elimination.