Ri. Grauch et al., HOGTUVAITE, A NEW BERYLLIAN MEMBER OF THE AENIGMATITE GROUP FROM NORWAY, WITH NEW X-RAY DATA ON AENIGMATITE, Canadian Mineralogist, 32, 1994, pp. 439-448
Hogtuvaite, essentially (Ca, Na)2 (Fe2+, Fe3+, Ti, Mg, Mn, Sn)6 (Si, B
e, Al)6 O20, is a new beryllian member of the aenigmatite group that w
as discovered in Nordland County, Norway. It is a metamorphic mineral,
hosted by Proterozoic granitic gneisses and mafic pegmatites of metam
orphic origin. Compositional variations within and between gneiss-host
ed samples of hogtuvaite are minimal; however, pegmatite-hosted sample
s of hogtuvaite are significantly different, containing less Al and Sn
, and more Ti and Mn, than those from the gneisses. The composition of
type hogtuvaite (in wt.%) is CaO 10.44, Na2O 1.52, FeO 28.06, Fe2O3 1
9.03, TiO2 2.77, MgO 0.42, MnO 0.27, SnO2 0.53, SiO2 31.60, BeO 2.65,
Al2O3 2.64. Hogtuvaite forms black, elongate, poikiloblastic crystals.
It has a dark green streak, an uneven fracture, two good cleavage dir
ections, and a nonmetallic subadamantine luster. It is nonmagnetic, is
not fluorescent, and does not react to most common acids and bases. H
owever, it does dissolve slowly in cold hydrofluoric acid. Its measure
d density is 3.85 g/cm3, and the calculated density is 3.98 g/cm3. The
mineral is opaque to subtransparent, biaxial negative (?) with a larg
e 2V, strongly pleochroic (bronze to green) and has alpha' 1.78 and ga
mma' 1.82. It is triclinic (pseudo-monoclinic), space group P1BAR, wit
h a 10.317(1), b 10.724(1) c 8.855(1) angstrom, alpha 105.77(1)degrees
, beta 96.21(1)degrees, gamma 124.77(1)degrees, V 730.4(1) angstrom3,
and Z = 2. All samples are intensely polysynthetically twinned. The st
rongest seven X-ray powder-diffraction lines [d in angstrom(1)(hkl)] a
re 2.5293(100)(420BAR), 8.048(90)(010), 2.0979(63)(251BAR), 2.9247(59)
(031BAR), 2.6761(48)(241BAR), 2.0747(47)(411BAR) and 3.125(46)(021). A
new and uniquely indexed set of X-ray powder diffraction data for aen
igmatite is presented. The name hogtuvaite is inspired by the highest
peak near die type locality.