SYNTHESIS AND STRUCTURE OF NOVEL HEXANUCLEAR IRON(III) COMPLEXES WITHMU-HYDROXO-BIS(MU-AMINO ACID-O,O')DIIRON CORES

Authors
TOKII T IDE K NAKASHIMA M KOIKAWA M
Citation
T. Tokii et al., SYNTHESIS AND STRUCTURE OF NOVEL HEXANUCLEAR IRON(III) COMPLEXES WITHMU-HYDROXO-BIS(MU-AMINO ACID-O,O')DIIRON CORES, Chemistry Letters, (3), 1994, pp. 441-444
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
3
Year of publication
1994
Pages
441 - 444
Database
ISI
SICI code
0366-7022(1994):3<441:SASONH>2.0.ZU;2-Z
Abstract
Novel hexanuclear iron(III) complexes with Fe-2(mu-OH)(mu-RCOO)(2) moi ety in the molecule (where RCOO is an amphoteric ion of beta-alanine ( 1) or glycylglycine) have been prepared. The crystal structure of 1 co nsists of two mu-hydroxo-bis(mu-beta-alanine-O,O')diiron(III) cores an d two iron(III) ions bridged by mu-oxo ions at each iron(III) site in the cores.