3-CENTER SELENIUM INTERACTION IN ELECTROCHEMICAL OXIDATION OF A LINEAR TRISSELENIDE, 2,6-BIS(PHENYLSELENOMETHYL)PHENYL PHENYL SELENIDE, ANDSE-MONOOXYGENATION FROM HYDROLYSIS OF ITS SULFURIC-ACID-SOLUTION

Authors
FUJIHARA H HIGUCHI Y MIMA H FURUKAWA N
Citation
H. Fujihara et al., 3-CENTER SELENIUM INTERACTION IN ELECTROCHEMICAL OXIDATION OF A LINEAR TRISSELENIDE, 2,6-BIS(PHENYLSELENOMETHYL)PHENYL PHENYL SELENIDE, ANDSE-MONOOXYGENATION FROM HYDROLYSIS OF ITS SULFURIC-ACID-SOLUTION, Chemistry Letters, (3), 1994, pp. 619-622
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
3
Year of publication
1994
Pages
619 - 622
Database
ISI
SICI code
0366-7022(1994):3<619:3SIIEO>2.0.ZU;2-L
Abstract
The cyclic voltammogram of a new trisselenide, 2,6-bis(phenylselenomet hyl)phenyl phenyl selenide (1), showed the reversible electrochemical oxidation with low oxidation potential which is attributed to the thre e-center selenium participation. The monoselenoxide of 1 was formed in the hydrolysis of coned H2SO4 solution of 1, while the MCPBA oxidatio n of 1 gave a mixture of the corresponding mono- and bisselenoxides.