Y. Cohen et I. Riess, PREPARATION OF OXYNITRIDE THIN-FILMS OF BANB(OYN)X AND LANB(OYN2)X USING REACTIVE SPUTTERING FROM MULTIPHASE POWDER TARGETS, Materials science & engineering. B, Solid-state materials for advanced technology, 25(2-3), 1994, pp. 197-202
Thin films of BaNb(O(y)N)x and LaNb(O(y)N2)x have been prepared by rea
ctive sputtering. The targets used were multiphase ones. A wide anion
composition range is obtained, including the more difficult to obtain
compositions having high concentrations of nitrogen. The Ba based film
s exhibit a crystalline structure with a lattice parameter slightly la
rger than that reported for bulk BaNbO2N. The La based films are amorp
hous. The films have a low electronic conductivity. The stoichiometric
Ba based films are stable on Si in a reducing atmosphere up to approx
imately 875-degrees-C, while the La based ones are stable up to approx
imately 480-degrees-C.