While it has been established that the elastic moduli and compliances
of anisotropic and isotropic materials should be positive for thermody
namic reasons, no condition related to the values of Poisson's ratio h
as yet been established. However, it is generally accepted that for is
otropic materials Poisson's ratio should vary between - 1.0 and 0.5, w
hereas for orthotropic materials various conditions have been introduc
ed relating the different components of the anisotropic Poisson's rati
o with the remaining elastic constants of the material. In this paper,
limits for Poisson's ratio of body-centred cubic (bcc) polycrystallin
e materials are determined, based on the modes of deformation of a typ
ical unit cell of the material subjected to a uniform external loading
arbitrarily oriented relative to the principal axes of the crystal. I
t is shown that the values of Poisson's ratio thus established correla
te satisfactorily with experimental values of this constant. The proce
dure can be readily applied to other structural units of polycrystalli
ne bodies.