SONOCHEMICAL SYNTHESIS OF C60H2

Citation
D. Mandrus et al., SONOCHEMICAL SYNTHESIS OF C60H2, JOURNAL OF PHYSICAL CHEMISTRY B, 101(2), 1997, pp. 123-128
Citations number
34
Categorie Soggetti
Chemistry Physical
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
101
Issue
2
Year of publication
1997
Pages
123 - 128
Database
ISI
SICI code
1089-5647(1997)101:2<123:SSOC>2.0.ZU;2-A
Abstract
C60H2 has been synthesized by ultrasonically irradiating solutions of C-60 in decahydronaphthalene. This synthesis can be understood as a se condary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventua l disappearance of both C-60 and C60H2 from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the comple te absence of more highly hydrogenated derivatives, suggests that the C-60 experiences a high-energy environment during ultrasonic irradiati on.