NOVEL FLOW-INJECTION CHANNEL FLOW CELL FOR THE INVESTIGATION OF PROCESSES AT SOLID-LIQUID INTERFACES .2. EXPERIMENT

A novel ''flow injection'' channel flow cell, which enables the study of transient phenomena at diverse solid/liquid interfaces, is describe d. The cell is comprised of a rectangular duct through which solution flows under laminar flow conditions. In one wall of the duct is embedd ed the solid substrate of interest, and directly adjacent to this is t he detector electrode, The solution species of interest enters the pri mary channel flow system from a secondary flow upstream of the solid s ubstrate, located in the opposite wall, without seriously disrupting t he well-defined flow profile in the former. The amount of the species injected, and the extent of any reaction with the solid substrate, is determined at the downstream detector electrode. Thus, the flow inject ion channel flow cell is similar to a double channel electrode but whe re the injection slit performs the function of the generator electrode (introducing a reactant species into the channel at a precise time), The rise time of the transient was comparable to a double channel elec trode of analogous geometry (in which the generator electrode mimics t he injection slit), and the detector current dies away to zero almost instantly once the injection is turned off. The variation in steady-st ate current with flow rate was shown to agree excellently with a theor etical description of the cell(1) without the need for any adjustable parameters, The cell was successfully used to monitor the reaction bet ween the dye orange G and virgin cotton cloth.