S. Gallet et al., GEOCHEMICAL CHARACTERIZATION OF THE LUOCHUAN LOESS-PALEOSOL SEQUENCE,CHINA, AND PALEOCLIMATIC IMPLICATIONS, Chemical geology, 133(1-4), 1996, pp. 67-88
Chemical (major and trace element) and isotopic (Sr, Nd) analyses of t
he Luochuan loess-paleosol sequence in China were performed in order t
o examine the following problems: (1) potential source heterogeneity;
(2) element behavior during pedogenesis; (3) paleoclimatic implication
s; and (4) the use of loess data to determine the average composition
of the upper continental crust. New results clearly indicate that Rb,
Sr, U and Ce abundances are severely depleted in paleosols relative to
their ''parental'' loess. The behavior of these elements is strongly
controlled by the breakdown of primary minerals such as carbonate (Sr)
or by alteration processes in highly oxidizing environments (Ce and U
). The pattern of element variations through the upper section of the
Luochuan sequence mimics the magnetic susceptibility signal both in po
sition and in intensity, thus reinforcing the pedogenetic origin of th
e enhanced magnetic susceptibility in paleosols. All loess samples dis
play highly uniform REE patterns (except for Ce) characterized by the
upper continental crust (UCC) ratios: (La/Yb)(N) approximate to 10 and
Eu/Eu approximate to 0.66. The paleosol REE patterns are similar to
those of the loess, with the same LREE/HREE fractionation, but they al
so show distinct and variable negative Ce anomalies. Nd and Sr isotopi
c compositions are rather uniform in both loess and paleosols and do n
ot vary with stratigraphic position (epsilon Nd = -10.5 to -9.2; Sr-87
/Sr-86 = 0.715 to 0.719). The isotopic homogeneity in the Luochuan seq
uence strongly suggests a uniform source region during the entire peri
od of deposition since similar to 800 ka ago to the present. Several c
onclusions may be drawn from the present study: (1) No geochemical dis
tinction can be made between loess layers L1 to L7. The sources and th
e dust storm trajectories must have been essentially the same for the
last 800 ka. (2) Some elements (e.g., Ca, Rb, Sr, U, Ce) are strongly
fractionated by pedogenesis between loess and paleosols. Ce mobility i
n soils is clearly demonstrated but the process responsible for this l
eaching is still poorly understood. (3) Systematic variations of eleme
nt abundances and ratios between loess and paleosols can be used as ch
emical indicators for pedogenetic intensity and so for paleoclimatic c
hange. These chemical indicators serve a function similar to that of o
xygen isotopes in deep-sea sediments (pelagic foraminifera), or that o
f magnetic susceptibility in loess sequences. They are different recor
ders of paleoclimatic change. (4) The striking uniformity of REE patte
rns and La/Th ratios in the Luochuan loess and paleosols, as well as i
n loess worldwide, is an excellent starting point for estimating the a
verage composition of the upper continental crust.