PHOTOREACTIONS OF PALLADIUM PHOSPHINE COMPLEX WITH CHLOROALKANE - PRODUCTION OF ETHYLENE WITH 1,2-DICHLOROETHANE AND NOVEL PHOTOCHROMIC BEHAVIOR

Authors
TSUBOMURA T ITSUKI A HOMMA M SAKAI K
Citation
T. Tsubomura et al., PHOTOREACTIONS OF PALLADIUM PHOSPHINE COMPLEX WITH CHLOROALKANE - PRODUCTION OF ETHYLENE WITH 1,2-DICHLOROETHANE AND NOVEL PHOTOCHROMIC BEHAVIOR, Chemistry Letters, (4), 1994, pp. 661-664
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1994
Pages
661 - 664
Database
ISI
SICI code
0366-7022(1994):4<661:POPPCW>2.0.ZU;2-R
Abstract
Photoirradiation on [Pd-2(0)(dppm)(3)] (dppm = bis(diphenylphosphino)m ethane) in 1,2-dichloroethane solution with visible light yields [(Pd2 Cl2)-Cl-I(dppm)(2)] (2) and ethylene quantitatively. Irradiation of 2 in various solutions shows interesting photochromic behavior.