PALLADIUM-CATALYZED FORMATION OF AROYLCOBALT COMPLEXES FROM IODOARENES AND TETRACARBONYLCOBALTATE(-1) ANION AND SYNTHESES OF THE MODEL INTERMEDIATE COMPLEXES

Authors
MISUMI Y ISHII Y HIDAI M
Citation
Y. Misumi et al., PALLADIUM-CATALYZED FORMATION OF AROYLCOBALT COMPLEXES FROM IODOARENES AND TETRACARBONYLCOBALTATE(-1) ANION AND SYNTHESES OF THE MODEL INTERMEDIATE COMPLEXES, Chemistry Letters, (4), 1994, pp. 695-698
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1994
Pages
695 - 698
Database
ISI
SICI code
0366-7022(1994):4<695:PFOACF>2.0.ZU;2-R
Abstract
Anion complex [Co(CO)(4)](-) reacted with iodoarenes to form aroylcoba lt complexes in the presence of a palladium catalyst and excess PPh(3) . As models of the intermediate of this reaction, Pt-Co and Pd-Co dinu clear complexes were synthesized from reactions of [Co(CO)(4)](-) with Pt(Ar)(OTf)(PPh(3))(2) and Pd(Ar)(OTf)(PMe(3))(2), respectively, and their crystal structures were determined by X-ray analysis.