A NOVEL TRANSAMINATION INDUCED BY TERPYRIDINE LIGAND COORDINATED ON COBALT(III) ION
Citation
K. Jitsukawa et al., A NOVEL TRANSAMINATION INDUCED BY TERPYRIDINE LIGAND COORDINATED ON COBALT(III) ION, Chemistry Letters, (7), 1994, pp. 1169-1172
Categorie Soggetti
Chemistry
SICI code
0366-7022(1994):7<1169:ANTIBT>2.0.ZU;2-#
Abstract
The reaction of salicylidene-l-alanine with the Co(III) complex involv
ing 2,2':6',2''-terpyridine (terpy) in aqueous ethanol solution afford
ed a peculiar transamination to form the complex, [Co(alpha-hydroxy sa
licylidene-o-hydroxybenzplamine) (terpy)](+), whose structure has been
confirmed by X-ray structure analysis and positive FAB mass spectrome
try.