FRAGMENTATION OF TRIPLE CUBANE-FRAMEWORK IN [(CP(ASTERISK)RH)(4)MO4O16] (CP(ASTERISK)=ETA(5)-C(5)ME(5)) BY MESH INTO TETRANUCLEAR PARTS IN [(CP(ASTERISK)RH(MU-SME)(3)MOO)2(MU-O)2] AND [(CP(ASTERISK)RH(MU-SME)3MOO)2-(MU-O)(MU-S)] PROVIDING A NOVEL SYSTEM FOR STUDYING STEREODYNAMICS OF THIOLATE COMPLEXES

Authors
XI RM WANG B ABE M OZAWA Y ISOBE K
Citation
Rm. Xi et al., FRAGMENTATION OF TRIPLE CUBANE-FRAMEWORK IN [(CP(ASTERISK)RH)(4)MO4O16] (CP(ASTERISK)=ETA(5)-C(5)ME(5)) BY MESH INTO TETRANUCLEAR PARTS IN [(CP(ASTERISK)RH(MU-SME)(3)MOO)2(MU-O)2] AND [(CP(ASTERISK)RH(MU-SME)3MOO)2-(MU-O)(MU-S)] PROVIDING A NOVEL SYSTEM FOR STUDYING STEREODYNAMICS OF THIOLATE COMPLEXES, Chemistry Letters, (7), 1994, pp. 1177-1180
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1994
Pages
1177 - 1180
Database
ISI
SICI code
0366-7022(1994):7<1177:FOTCI[>2.0.ZU;2-E
Abstract
Reaction of the triple cubane-type cluster [((CPRh)-Rh-)(4)Mo4O16] wi th MeSH gave two tetranuclear complexes of [{CpRh(mu-SMe)(3)MoO}2(mu- O)(2)] and [{CpRh-(mu-SMe)(3)MoO}(2)(mu-O)(mu-S)] which were characte rized by X-ray structural analysis. The stereodynamics of the two comp lexes was studied by variable-temperature H-1 and O-17 NMR as well as C-13 NMR spectroscopy.