A HETEROTRIMETALLIC SULFIDE CLUSTER HAVING A LINEAR RH(III)...W(VI)...CU(I) FRAMEWORK OF AN OCTAHEDRAL-TETRAHEDRAL-TRIGONAL PLANAR SEQUENCE

Authors
OGO S SUZUKI T OZAWA Y ISOBE K
Citation
S. Ogo et al., A HETEROTRIMETALLIC SULFIDE CLUSTER HAVING A LINEAR RH(III)...W(VI)...CU(I) FRAMEWORK OF AN OCTAHEDRAL-TETRAHEDRAL-TRIGONAL PLANAR SEQUENCE, Chemistry Letters, (7), 1994, pp. 1235-1238
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1994
Pages
1235 - 1238
Database
ISI
SICI code
0366-7022(1994):7<1235:AHSCHA>2.0.ZU;2-P
Abstract
A heterotrimetallic sulfide cluster with an organometallic group, [Cp Rh{P(OEt)(3)}(mu-S)(2)W(mu-S)2CuCl] (Cp=eta(5)-C(5)Me(5)), was prepar ed stepwise by using mononuclear units of organorhodium(III), thiotung state(VI), and chlorocopper(I). X-ray crystal structure analysis revea led that the cluster possesses a linear sequence of middle (Rh), early (W), and late (Cu) transition metal atoms with octahedral, tetrahedra l, and trigonal planar coordination geometries, respectively.