In this paper we describe the characteristics of new solid electrolyti
c capacitors (aluminum or tantalum type) in which the conventional cou
nterelectrode is replaced by conducting polymer A thick layer of polyp
yrrole is directly deposited on the dielectric surface by chemical oxi
dative polycondensation. By a precise control of the deposit condition
s of the polymer we obtain a high specific capacitance value (approxim
ately 2muFV/mm3). The final capacitor device has excellent impedance-f
requency characteristics comparable to the ceramic capacitors. We demo
nstrate that the stability of the capacitors is a function of the dopi
ng ion.